Friday 26th of April 2024

the plastic curse…..

bottlesbottles
Recycled plastic bottles leach more chemicals into drinks, review finds


More chemicals being released by reused plastic could indicate need for ‘super clean’ recycling process

 

A widely used kind of recycled plastic bottle passes more potentially harmful chemicals into their contents than newly manufactured bottles, researchers have warned.

Researchers from Brunel University London found 150 chemicals that leached into drinks from plastic bottles, with 18 of those chemicals found in levels exceeding regulations.

 

And they found that drinks bottled using recycled Polyethylene Terephthalate (PET) can contained higher concentrations of chemicals than those bottled using new PET, which suggests that problems with the recycling process may be causing contamination.

They are calling for more careful recycling methods to remove the potentially harmful chemicals.

The thermoplastic PET is the third most widely used type of plastic in food packaging, with one of its most popular end uses in single-use drinks bottles. Such bottles are also one of the most commonly found forms of plastic litter, leading to a number of initiatives to increase levels of PET recycling. A recent EU directive called for PET bottles to contain at least 30% recycled content by 2030.

But PET is also known for being the source of a number of potential chemical contaminants, including endocrine disruptors such as Bisphenol A, which can cause reproductive disorders, cardiovascular problems and cancer, among other ill effects.

The researchers reviewed 91 studies from around the world looking at chemical contamination from plastic bottles. Dr Eleni Iacovidou, a lecturer from Brunel’s centre for pollution research and policy, who led the study, said: “We found these chemicals can come from various sources, such as the catalysts and additives used during production and degradation during PET production, and degradation that can happen across a bottle’s lifecycle.”

In recycled PET bottles, many of the contaminants found had arisen as a result of contamination of the feedstock, including labels, according to the paper, published in the Journal of Hazardous Materials. The researchers wrote: “This evidence implies that highly recyclable products, such as PET drink bottles, can be inapt for closed-loop recycling when poorly designed, indicating the need for greater adoption of design-for-recycling principles and improvements at the waste-management infrastructure level.”

In particular, to reduce the number of chemicals found in bottled drinks, the study suggests that a technology known as the “super cleaning” process could be used, which uses a three-stage process to clean old plastics before recycling – a high-temperature wash, a gas wash, and a chemical wash.

Iacovidou said: “Recycling processes already include the cleaning of the bottles before turning them into secondary raw material for use. By investing in new super-cleaning technologies, we can maximise the likelihood of decontaminating recycled PET to levels similar to virgin PET.”

As ever though, the ultimate solution to the problem is for society to begin an end to the use of PET altogether, Iacovidou said.

“We all have a responsibility to bear. We need to start thinking about how to prevent the use of PET bottles in our households by investing, for example, in water filters, or large water containers and learning how to dispose of our plastic waste properly,” she said.

“If we reduce our consumption of PET then we will drive change further up the system. Less demand equals less production in the first place.”

 

READ MORE:

https://www.theguardian.com/environment/2022/mar/18/recycled-plastic-bottles-leach-more-chemicals-into-drinks-review-finds

 

 

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Plastic winds up everywhere—from the top of Mount Everest to remote Antarctica. Every year, millions of tons of discarded plastic also wash into the ocean.

 

Research about ocean plastic is swelling, too, from 46 papers in 2011 to 853 in 2019, according to a UNESCO science report published last week. The report found that ocean plastic research grew much faster than any of the other 55 development-related topics it tracked. “It has really skyrocketed in recent years,” says Utrecht University's Erik Van Sebille, who uses plastic particles to trace ocean currents.

 

But gaps remain in the research. Journals get many papers about “the presence of plastic on beaches, on the seabed, or in animals, but not [many] about sources or solutions,” says Ángel Borja, a marine ecologist at the AZTI research center in Spain.

 

The ecological effects of plastic pollution are another hot research topic. Plastic itself is inert, but often contains toxic additives such as flame retardants, pigments, or chemicals to make plastic more flexible and durable. “These additives are what we're worried about,” says Carmen Morales, an ecotoxicologist at the University of Cádiz's Marine Litter Lab, who in a study published last week found that takeout food and drink packaging is the most pervasive source of ocean plastic.

 

Researchers are also concerned about animals that eat plankton-size particles without deriving any nutrition. Nanoplastic particles, small enough to penetrate tissues, may be the most harmful of all. Yet the overall ecotoxicological effects of plastic are poorly understood. Regardless, plastic pollution is a pressing problem, says Bart Koelmans, an aquatic ecologist at Wageningen University. “It's an eyesore to have all this plastic on beaches,” he says. “For many people, that is enough to be concerned.”

 

READ MORE:

SCIENCE • 18 Jun 2021 • Vol 372, Issue 6548

 

 

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a dangerous solution?...

 NEW Zinc catalyst dismantling plastics at room temperature.

 

As a chemist who works with one of the presented methods of "splitting" PET into its components, I can add that the process works. The issue is how to get the materials sorted for a good base to work with. If there's a rather low percentage of, e.g., PE contained, this will not be broken down, and other materials also won't. And it can be difficult to clean the products of the reaction. Sorting of materials is actually the major problem for any plastic recycling. If it was possible to separate the materials up to a 99.99% purity, recycling would be much easier. But anything below this purity will either lead to expensive clean-up steps, or will prevent recycling at all. By the way, "bisphenol" is pronounced differently (not bise-phenol, but biss-phenol), and it's unfortunately one potent endocrine disruptor which is under strict limits in most countries.

Human Isomer

SEE MORE:
https://www.youtube.com/watch?v=hLBBTX6ARLY

 

 

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